GHS标准SDS报告-安全数据表样例
GHS是TheGloballyHarmonizedSystemofClassificationandLabellingofChemicals首字母缩写，翻译成中文就是全球化学品统一分类及标签制度。GHS要求MSDS上有关产品的危险信息必须参照GHS的要求标明。有关GHS要...
GHS是TheGloballyHarmonizedSystemofClassificationandLabellingofChemicals首字母缩写，翻译成中文就是全球化学品统一分类及标签制度。GHS要求SDS上有关产品的危险信息必须参照GHS的要求标明。有关GHS要求的SDS具体格式，现附样例一： ChemicalStuff
(GHSMSDSExample)
GHSSAFETYDATASHEET
1.Identification
ProductName:ChemicalStuff
Synonyms: MethyltoxySolution
CASNumber: 000-00-0
ProductUse: OrganicSynthesis
Manufacturer/Supplier: MyCompany
Address: MyStreet,Mytown,TX00000
GeneralInformation: 713-000-0000
TransportationEmergencyNumber:CHEMTREC:800-424-9300
2.HazardsIdentification
GHSClassification: HealthEnvironmentalPhysical AcuteToxicity-Category2(inhalation),Category3(oral/dermal)
EyeCorrosion-Category1
SkinCorrosion-Category1
SkinSensitization-Category1
Mutagenicity-Category2
Carcinogenicity-Category1B
Reproductive/Developmental-Category2
TargetOrganToxicity(Repeated)-Category2AquaticToxicity-Acute2FlammableLiquid-Category2
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GHSLabel: Symbols:flame,skullandcrossbones,corrosion,healthhazard
HazardStatements
DANGER!
HighlyFlammableLiquidandVapor.
Fatalifinhaled.
Causessevereskinburnsandeyedamage.
Maycauseallergicskinreaction.
Toxicifswallowedandincontactwithskin
Maycausecancer.
Suspectedofdamagingtheunbornchild.
Suspectedofcausinggeneticdefects.
Maycausedamagetocardiovascular,respiratory,nervous,andgastrointestinalsystemsandliverandbloodthroughprolongedorrepeatedexposure.
Toxictoaquaticlife.PrecautionaryStatements
Donoteat,drinkorusetobaccowhenusingthisproduct.
Donotbreathemist/vapors.
Keepcontainertightlyclosed.
Keepawayfromheat/sparks/openflame.-Nosmoking.
Wearrespiratoryprotection,protectiveglovesandeye/faceprotection.
Useonlyinawell-ventilatedarea.
Takeprecautionarymeasuresagainststaticdischarge.
Useonlynon-sparkingtools.
Storecontainertightlyclosedincool/well-ventilatedplace.
Washthoroughlyafterhandling.
3.Composition/InformationonIngredients
Component CASNumber Weight%
Methyltoxy 000-00-0 80
(SeeSection8forExposureLimits)
4.FirstAidMeasures
Eye:Eyeirritation.Flushimmediatelywithlargeamountsofwaterforatleast15minutes.Eyelidsshouldbeheldawayfromtheeyeballtoensurethoroughrinsing.Getimmediatemedicalattention.
Skin:Itchingorburningoftheskin.Immediatelyflushtheskinwithplentyofwaterwhileremovingcontaminatedclothingandshoes.Getimmediatemedicalattention.Washcontaminatedclothingbeforereuse.
Inhalation:Nasalirritation,headache,dizziness,nausea,vomiting,heartpalpitations,breathingdifficulty,cyanosis,tremors,weakness,redflushingofface,irritability.Removeexposedpersonfromsourceofexposuretofreshair.Ifnotbreathing,clearairwayandstartcardiopulmonaryresuscitation(CPR).Avoidmouth-to-mouthresuscitation.
Ingestion:Getimmediatemedicalattention.Donotinducevomitingunlessdirectedbymedicalpersonnel.
5.FireFightingMeasures
SuitableExtinguishingMedia:Usedrychemical,foam,orcarbondioxidetoextinguishfire.Watermaybeineffectivebutshouldbeusedtocoolfire-exposedcontainers,structuresandtoprotectpersonnel.Usewatertodilutespillsandtoflushthemawayfromsourcesofignition.
FireFightingProcedures:Donotflushdownsewersorotherdrainagesystems.ExposedfirefightersmustwearNIOSH-approvedpositivepressureself-containedbreathingapparatuswithfull-facemaskandfullprotectiveclothing.
UnusualFireandExplosionHazards:Dangerouswhenexposedtoheatorflame.Willformflammableorexplosivemixtureswithairatroomtemperature.Vapororgasmayspreadtodistantignitionsourcesandflashback.Vaporsorgasmayaccumulateinlowareas.Runofftosewermaycausefireorexplosionhazard.Containersmayexplodeinheatoffire.Vaporsmayconcentrateinconfinedareas.Liquidwillfloatandmayreigniteonthesurfaceofwater.
CombustionProducts:Irritatingortoxicsubstancesmaybeemitteduponthermaldecomposition.Thermaldecompositionproductsmayincludeoxidesofcarbonandnitrogen.
6:AccidentalReleaseMeasures
Keepunnecessarypeopleaway;isolatehazardareaanddenyentry.Stayupwind;keepoutoflowareas.(AlsoseeSection8).
Vaporprotectiveclothingshouldbewornforspillsandleaks.Shutoffignitionsources;noflares,smokingorflamesinhazardarea.Smallspills:Takeupwithsandorothernoncombustibleabsorbentmaterialandplaceintocontainersforlaterdisposal.Largespills:Dikefaraheadofliquidspillforlaterdisposal.
Donotflushtosewerorwaterways.Preventreleasetotheenvironmentifpossible.RefertoSection15forspill/releasereportinginformation.
7.HandlingandStorage
Handling
Donotgetineyes,onskinoronclothing.Donotbreathevaporsormists.Keepcontainerclosed.Useonlywithadequateventilation.Usegoodpersonalhygienepractices.Washhandsbeforeeating,drinking,smoking.Removecontaminatedclothingandcleanbeforere-use.Destroycontaminatedbeltsandshoesandotheritemsthatcannotbedecontaminated.
Keepawayfromheatandflame.Keepoperatingtemperaturesbelowignitiontemperaturesatalltimes.Usenon-sparkingtools.
Storage
Storeintightlyclosedcontainersincool,dry,well-ventilatedareaawayfromheat,sourcesofignitionandincompatibles.Groundlinesandequipmentusedduringtransfertoreducethepossibilityofstaticspark-initiatedfireorexplosion.Storeatambientorlowertemperature.Storeoutofdirectsunlight.Keepcontainerstightlyclosedanduprightwhennotinuse.Protectagainstphysicaldamage.
Emptycontainersmaycontaintoxic,flammableandexplosiveresidueorvapors.Donotcut,grind,drill,orweldonornearcontainersunlessprecautionsaretakenagainstthesehazards.
8.ExposureControls/PersonalProtection
ExposureLimits
Component,Methyltoxy -TWA:3ppm (skin)-STEL:C15ppm(15min.)
EngineeringControls:Localexhaustventilationmaybenecessarytocontrolaircontaminantstotheirexposurelimits.Theuseoflocalventilationisrecommendedtocontrolemissionsnearthesource.Providemechanicalventilationforconfinedspaces.Useexplosion-proofventilationequipment.
PersonalProtectiveEquipment(PPE)
EyeProtection:Wearchemicalsafetygogglesandfaceshield.Haveeye-washstationsavailablewhereeyecontactcanoccur.
SkinProtection:Avoidskincontact.Wearglovesimpervioustoconditionsofuse.Additionalprotectionmaybenecessarytopreventskincontactincludinguseofapron,faceshield,bootsorfullbodyprotection.Asafetyshowershouldbelocatedintheworkarea.Recommendedprotectivematerialsinclude:ButylrubberandforlimitedcontactTeflon.
RespiratoryProtection:Ifexposurelimitsareexceeded,NIOSHapprovedrespiratoryprotectionshouldbeworn.ANIOSHapprovedrespiratorfororganicvaporsisgenerallyacceptableforconcentrationsupto10timesthePEL.Forhigherconcentrations,unknownconcentrationsandforoxygendeficientatmospheres,useaNIOSHapprovedair-suppliedrespirator.Engineeringcontrolsarethepreferredmeansforcontrollingchemicalexposures.Respiratoryprotectionmaybeneededfornon-routineoremergencysituations.RespiratoryprotectionmustbeprovidedinaccordancewithOSHA29CFR1910.134.
9.PhysicalandChemicalProperties
Flashpoint:2oC(35oF)
AutoignitionTemperature:480oC(896oF)
BoilingPoint:77oC(170.6oF)@760mmHg
MeltingPoint:-82oC
VaporPressure:100.0mmHg@23oC
VaporDensity(Air=1):1.7;air=1
%SolubilityinWater:10@20ºC
PourPoint:NA
MolecularFormula:Mixture
Odor/Appearance:Clear,colorlessliquidwithmild,pungentodor.
LowerFlammabilityLimit:>3.00%
UpperFlammabilityLimit:<15.00%
SpecificGravity:0.82g/ml@20oC
%Volatile:100
EvaporationRate(Water=1):5(ButylAcetate=1)
Viscosity:0.3cP@25oC
Octanol/WaterPartitionCoefficient:logKow:0.5
pH:7,8%aqueoussolution
MolecularWeight:Mixture
10.StabilityandReactivity
Stability/Incompatibility:Incompatiblewithammonia,amines,bromine,strongbasesandstrongacids.
HazardousReactions/DecompositionProducts:Thermaldecompositionproductsmayincludeoxidesofcarbonandnitrogen.
11.ToxicologicalInformation
SignsandSymptomsofOverexposure:Eyeandnasalirritation,headache,dizziness,nausea,vomiting,heartpalpitations,difficultybreathing,cyanosis,tremors,weakness,itchingorburningoftheskin.
AcuteEffects:
EyeContact:maycausesevereconjunctivalirritationandcornealdamage.
SkinContact:maycausereddening,blisteringorburnswithpermanentdamage.Harmfulifabsorbedthroughtheskin.Maycauseallergicskinreaction.
Inhalation:maycausesevereirritationwithpossiblelungdamage(pulmonaryedema).
Ingestion:maycauseseveregastrointestinalburns.
TargetOrganEffects:Maycausegastrointestinal(oral),respiratorytract,nervoussystemandbloodeffectsbasedonexperimentalanimaldata.Maycausecardiovascularsystemandlivereffects.
ChronicEffects:basedonexperimentalanimaldata,maycausechangestogeneticmaterial;adverseeffectsonthedevelopingfetusoronreproductionatdosesthatweretoxictothemother.MethyltoxyisclassifiedbyIARCasgroup2BandbyNTPasreasonablyanticipatedtobeahumancarcinogen.OSHAregulatesMethyltoxyasapotentialcarcinogen.
MedicalConditionsAggravatedbyExposure:preexistingdiseasesoftherespiratorytract,nervoussystem,cardiovascularsystem,liverorgastrointestinaltract.
AcuteToxicityValues
OralLD50(Rat)=100mg/kg
DermalLD50(Rabbit)=225-300mg/kg
InhalationLC50(Rat)=200ppm/4hr.,1100ppmvapor/1hr
12.EcologicalInformation
LC50(FatheadMinnows)=9mg/L/96hr.
EC50(Daphnia)=8.6mg/L/48hr.
Bioaccumulationisnotexpectedtobesignificant.Thisproductisreadilybiodegradable.
13.DisposalConsiderations
Assold,thisproduct,whendiscardedordisposedof,isahazardouswasteaccordingtoFederalregulations(40CFR261).ItislistedasHazardousWasteNumberZ000,listedduetoitstoxicity.Thetransportation,storage,treatmentanddisposalofthiswastematerialmustbeconductedincompliancewith40CFR262,263,264,268and270.Disposalcanoccuronlyinproperlypermittedfacilities.Refertostateandlocalrequirementsforanyadditionalrequirements,asthesemaybedifferentfromFederallawsandregulations.Chemicaladditions,processingorotherwisealteringthismaterialmaymakewastemanagementinformationpresentedintheMSDSincomplete,inaccurateorotherwiseinappropriate.
14.TransportInformation
U.S.DepartmentofTransportation(DOT)
ProperShippingName:Methyltoxy
HazardClass:3,6.1
UN/NANumber:UN0000
PackingGroup:PG2
LabelsRequired:FlammableLiquidandToxic
InternationalMaritimeOrganization(IMDG)
ProperShippingName:Methyltoxy
HazardClass:3Subsidiary6.1
UN/NANumber:UN0000
PackingGroup:PG2
LabelsRequired:FlammableLiquidandToxic
15.RegulatoryInformation
U.S.FederalRegulations
ComprehensiveEnvironmentalResponseandLiabilityActof1980(CERCLA):
Thereportablequantity(RQ)forthismaterialis1000pounds.Ifappropriate,immediatelyreporttotheNationalResponseCenter(800/424-8802)asrequiredbyU.S.FederalLaw.Alsocontactappropriatestateandlocalregulatoryagencies.
ToxicSubstancesControlAct(TSCA):AllcomponentsofthisproductareincludedontheTSCAinventory.
CleanWaterAct(CWA):MethyltoxyisahazardoussubstanceundertheCleanWaterAct.ConsultFederal,Stateandlocalregulationsforspecificrequirements.
CleanAirAct(CAA):MethyltoxyisahazardoussubstanceundertheCleanAirAct.ConsultFederal,Stateandlocalregulationsforspecificrequirements.
SuperfundAmendmentsandReauthorizationAct(SARA)TitleIIIInformation:
SARASection311/312(40CFR370)HazardCategories:
ImmediateHazard:X
DelayedHazard:X
FireHazard:X
PressureHazard:
ReactivityHazard:
Thisproductcontainsthefollowingtoxicchemical(s)subjecttoreportingrequirementsofSARASection313(40CFR372)
Component CASNumber Maximum%
Methyltoxy 000-00-0 80
StateRegulations
California:Thisproductcontainsthefollowingchemicals(s)knowntotheStateofCaliforniatocausecancer,birthdefectsorreproductiveharm:
Component CASNumber Maximum%
Methyltoxy 000-00-0 80
InternationalRegulations
CanadianEnvironmentalProtectionAct:AllofthecomponentsofthisproductareincludedontheCanadianDomesticSubstanceslist(DSL).
CanadianWorkplaceHazardousMaterialsInformationSystem(WHMIS):
ClassB-2FlammableLiquid
ClassD-1-BToxic
ClassD-2-ACarcinogen
ClassD-2-BChronicToxin
ClassECorrosive
ThisproducthasbeenclassifiedinaccordancewiththehazardcriteriaoftheControlledProductsRegulationsandtheMSDScontainsalltheinformationrequiredbytheControlledProductsRegulations.
EuropeanInventoryofExistingChemicals(EINECS):AllofthecomponentsofthisproductareincludedonEINECS.
EUClassification:FHighlyFlammable;TToxic;NDangeroustotheEnvironment
EURisk(R)andSafety(S)Phrases:
R11:Highlyflammable.
R23/24/25:Toxicbyinhalation,incontactwithskinandifswallowed.
R37/38:Irritatingtorespiratorysystemandskin.
R41:Riskofseriousdamagetoeyes.
R43:Maycausesensitizationbyskincontact.
R45:Maycausecancer.
R51/53:Toxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment.
S53:Avoidexposure-obtainspecialinstructionsbeforeuse.
S16:Keepawayfromsourcesofignition-NoSmoking.
S45:Incaseofaccidentorifyoufeelunwell,seekmedicaladviceimmediately(showthelabelwherepossible).
S9:Keepcontainerinawell-ventilatedplace.
S36/37:Wearsuitableprotectiveclothingandgloves.
S57:Useappropriatecontainertoavoidenvironmentalcontamination.
16.OtherInformation
NationalFireProtectionAssociation(NFPA)Ratings:ThisinformationisintendedsolelyfortheuseofindividualstrainedintheNFPAsystem.
Health:3
Flammability: 3
Reactivity:0
RevisionIndicator:NewMSDS
Disclaimer:Theinformationcontainedhereinisaccuratetothebestofourknowledge.MyCompanymakesnowarrantyofanykind,expressorimplied,concerningthesafeuseofthismaterialinyourprocessorincombinationwithothersubstances.
附加阅读资料： CLP是如何影响SDS的
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