英文SDS报告是什么样的符合GHS标准的化学品安全技术说明书样例_MSDS-MSDS哪里做-GHS SDS - 临安科达认证技术咨询服务

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英文SDS报告是什么样的符合GHS标准的化学品安全技术说明书样例

SafetyDataSheetThecontentandformatofthisSDSisaccordantwithGHSstandard.1.Identificationofthesubstance/preparationandofthecompany/undertaking.Productname:Anhydroussodiumsu...

1.Identificationofthesubstance/preparationandofthecompany/undertaking

.Productname: Anhydroussodiumsulfide.Applicationofthesubstance:AppliedinmanufacturingofPPS,pharmaceuticalintermediates,cosmeticintermediatesandfoodadditives.Italsocanbeusedinscientificexperiment.DoNOTuseitinawaywhichmaycontaminatefoodordoharmtohumanhealth..Manufacturer/Supplier:

.Address:

Tel: Fax:.Furtherinformationobtainablefrom:

.Informationincaseofemergency:

2.Hazardsidentification

.GHSclassificationaccordingtoAnnexⅡ:

Physicalhazards

Healthhazards

Environmentalhazards

Explosives-notclassified

Flammablegases-notclassified

Flammableaerosols-notclassified

Gasesunderpressure-notclassified

Flammableliquids-notclassified

Flammablesolids-notclassified

Self-reactivesubstancesandmixtures-notclassified

Pyrophoricliquids-notclassified

Pyrophoricsolids-1

Self-heatingsubstancesandmixtures-notclassified

Substancesandmixtures,whichincontactwithwater,emitflammablegases-notclassified

Oxidizingliquids-notclassified

Oxidizingsolids-notclassified

Organicperoxides-notclassified

Corrosivetometals-notclassified

Acutetoxicity(oral)-4

Acutetoxicity(dermal)-4

Acutetoxicity(inhalation)-notclassified

Skincorrosion/irritation-2

Seriouseyedamage/eyeirritation-2A

Respiratorysensitizer-notclassified

Skinsensitizer-notclassified

Germcellmutagenicity-notclassified

Carcinogenicity-notclassified

Toxictoreproduction-notclassified

Effectsonorvialactation-notclassified

STOTSE-notclassified

STOTRE-notclassified

Acutehazardstotheaquaticenvironment-1

Chronichazardstotheaquaticenvironment-notclassified

SafetyDataSheet

ThecontentandformatofthisSDSisaccordantwithGHSstandard.

.Signalword:Danger

.Symbol :

.HazardStatement:

H250:Catchesfirespontaneouslyifexposedtoair.H302:Harmfulifswallowed.H312:Harmfulincontactwithskin.H315:Causesskinirritation.H319:Causesseriouseyeirritation.H400:Verytoxictoaquaticlife..PrecautionaryStatements:

P210:Keepawayfromheat/sparks/openflames/hotsurfaces–Nosmoking.P222:Donotallowcontactwithair.P264:Washhandsthoroughlyafterhandling.P270 :Donoteat,drinkorsmokewhenusingthisproduct.P272:Contaminatedworkclothingshouldnotbeallowedoutoftheworkplace.P280 :Wearprotectivegloves(e.g.acidandalkaliresistantgloves)/protectiveclothing(e.g.antistaticprotectiveclothing) /eyeprotection/faceprotection.

P273 :Avoidreleasetotheenvironment.

.ResponsePrecautionaryStatements:

P335+P334 :Brushofflooseparticlesfromskin.Immerseincoolwater/wrapinwetbandages.P332+P313 :Ifskinirritationoccurs:Getmedicaladvice/attention.P362 :Takeoffcontaminatedclothingandwashbeforereuse.P305+P351+P338+P310:IFINEYES: Removecontactlensesifpresentandeasytodo.continuerinsing.Immediatelygetmedicaladvice/attention.P301+330+331+310 :IFSWALLOWED :Rinsemouthimmediately.DoNOT inducevomiting,getmedicalattentionimmediately.P304+P312 :IFINHALED :CallaPOISONCENTERordoctor/physicianifyoufeelunwell.P378:Useproperextinguishersforextinction(e.g.loess,sand,tapwater,etc.)..Storageprecautionarystatements:

P401:Storeinaclosedcontainerwithoutexposuretoair.DoNOTstoretogetherwithacidsoroxidants..Disposalprecautionarystatements:

P501:Disposeofcontents/containertorelevantlocalandnationalregulations.

3.Composition/informationoningredients

Productdescription:substance();preparation/mixture(√)

Ingredients

CAS

EINECS

%byweight

sodiumsulfide（Na₂S）

1313-82-2215-211-5

≥92%

sodiumsulfite（Na₂SO₃）

7757-83-7231-821-4≤0.8%

sodiumthiosulfate（Na₂S₂O₃）

7772-98-7231-867-5≤1.60%

sodiumcarbonate（Na₂CO₃）

497-19-8207-838-8≤1.50%

impurity

---- ≤0.050%

water（H₂O）

7732-18-5--≤4.10%

iron（Fe）

7439-89-6--0.0020%

4Firstaidmeasures

Personsusingthisproductshouldconsultaphysicianorothermedicalprofessionalifanaccidentinvolvingthisproductininjury.Specificfirst-aidmeasuresareasfollows:.EyesContact:Immediatelyraiseeyelidsandflushwithplentyofwateratleastfor15minutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.Ifirritationpersists,seekmedicalcare..SkinContact: Immediatelywatercontaminatedareawithplentyofwaterandsoap.Removeallcontaminatedclothingandwashthoroughlybeforereuse.Ifirritationpersists,getmedicalattention..Inhalation: Removetofreshair.CallaPOISONCENTERordoctor/physicianifyoufeelunwell..Ingestion:Donotinducevomitingwithoutprofessionalinstruction.Getmedicalattentionimmediately..Acuteeffectanddelayedeffect: Acuteeffect:Itcausesirritationtoskinandseriousirritationtoeyes.Incaseofingestion,itcauseirritationtogastrointestinaltract.Delayedeffect:Long-termorrepeatedexposuremaypoisoningasitmayreleasehydrogensulfideifcontactingcarbondioxide..Personalprotectiveequipment:Wearprotectivegloves(e.g.acidandalkaliresistantgloves).Wearrespiratorsandsafetygoggleswhenexposure limitsareexceededorworkinginadustyenvironment.

5.Fire-fightingmeasures

.Flashpoint:Notavailable.Flammable/ExplosiveLimits-LowerVol%:Notavailable.Flammable/ExplosiveLimits-UpperVol%:Notavailable.ExtinguishingMedia: Useloessorsandforsmallfire;usewaterforlargefire.DoNOTusCO₂asextinguishingmedia.Seekadvicefromlocalfire-fightingauthority..FireFightingEquipments:Firefightersmustwearself-containedbreathingapparatusandfullprotectiveequipment. .UnusualFireandExplosionHazards: Themixtureofairandthepowderofthisproductisexplosive.Itcanliberatehydrogensulfidegaseswhenreactingwithacids.Hydrogensulfidegasistoxicandflammable..HazardousCombustionProducts: Itcanliberatetoxicandirritatingfumefromcombustion(e.g.sulfurdioxideandhydrogensulfide).

6.Accidentalreleasemeasures

.Personalprecautions:UseproperpersonalprotectiveequipmentasindicatedinSection8..MeasuresforCleaning/Collection:

SmallSpill:Sweepupcarefullytoavoidgeneratingdust.Collectintobagsandtransfertoasafeplace.LargeSpill:Isolatecontaminatedareaandsetupawarningboard.Thepersonshandlingemergencyarerecommendedwearingprotectivemaskandclothing.DoNOTtouchspilledmaterial.Coverthespilledpowderwithplasticclothorcanvas.Trytorecycleit..EnvironmentalPrecautions: Keepcleaningrun-offsoutofmunicipalsewersandopenbodiesofwater.Complywithlocalandnationallawsandregulations.

7.Handlingandstorage

.Handling:Donotbreathevaporthatmaybeevolvedduringprocessing.Workersmustwearproperprotectiveequipmentsandmustoperatestrictlyaccordingtorelativerules.

.Informationaboutfire-andexplosionprotection:

Keepignitionsourcesaway—Donotsmoke.

.Storage:

.Requirementstobemetbystorerooms:Storeitinawell-ventilated,coolanddrystoreroom.Keepcontainerstightlysealed. DoNOTstoretogetherwithacidsoroxidants.

.AdditionalInformation: Thestoreroomshouldbeequippedwithproperfacilitiesforaccidentalleakageandfire.

8.Exposurecontrols/personalprotection

Ingredients

OSHAPEL-TWA

ACGIHTLV-TWA

sodiumsulfide（Na₂S）（CAS:1313-82-2）

NoavailableNoavailable

sodiumsulfite（Na₂SO₃）（CAS:7757-83-7）

NoavailableNoavailable

sodiumthiosulfate（Na₂S₂O₃）（CAS:7772-98-7）

NoavailableNoavailable

sodiumcarbonate（Na₂CO₃）（CAS:497-19-8）

NoavailableNoavailable

iron（Fe）（CAS: 7439-89-6）

Noavailable5mg/m³(ironoxides,fumeanddust)

.EngineeringControls:Useprocessenclosures,localexhaustventilation,orotherengineeringcontrolstokeepairbornelevelsbelowrecommendedexposurelimits.Ifuseroperationsgeneratedustorfume,useventilationtokeepexposuretoairbornecontaminantsbelowtheexposurelimit..PersonalProtectiveEquipments:

.ProtectionofHands:

Wearacidandalkaliresistantgloves..ProtectionofEyes:

Nospecialrequirementsundernormalconditions.Wearsafetyglasseswhendustorfumemaycontacteyes..RespiratoryProtection:Useanapprovedrespirator(e.g. self-inhalationfilter-typedustrespirator)ifexposurelimitsareexceededorifirritationorothersymptomsoccur..ProtectionofBody:

Wearacidandalkaliresistantuniforms..Generalprotectiveandhygienicmeasures:

Keepawayfromfoodstuffs,beveragesandfeed.Washhandsbeforebreaksandattheendofwork.Avoidcontactwitheyesandskin.

9.Physicalandchemicalproperties

GeneralInformation

Form

Granules(solid)

Color

Lightyellow

Odor

Slightlysmelly

BoilingRange

Notavailable

Meltingpoint/Meltingrange

1180℃(Na₂S)

Flashpoint

Notavailable

Self-igniting

Notavailable

Flammable/ExplosiveLimits-LowerVol%

Notavailable

Flammable/ExplosiveLimits-UpperVol%

Notavailable

Density（@15℃）

Approx.1.856

RelativeVapordensity

Notavailable

Vaporpressure

Notavailable

Solubilityin/MiscibilitywithWater

Solubleinwater

PH-Value

Notavailable

Viscosity(cSt@100℃)

Notavailable

10.Stabilityandreactivity

.ChemicalStability:Stableundernormaltemperaturesandpressures.

.HazardousDecompositionProducts: Itcanliberatetoxicandirritatingfumefromcombustion..Materialstoavoid:Acidsandstrongoxidants..HazardousPolymerizations:Willnotoccur. .ConditionstoAvoid:Light,long-timeexposuretoairandmoisture.

11.Toxicologicalinformation

.ProductToxicityData: Thetoxicitydataofthisproducthasnotbeendeterminedbytestingorresearch,buttorelevantliteratureandclassificationstandardinAnnex2ofGHS,thisproductistoxic.Thetoxicitydatashownbelowisforreferenceonly.

Ingredients

CAS

LD50/LC50

sodiumsulfide（Na₂S）

1313-82-2

AcuteOralLD50:300mg/kg(rat)

AcuteDermalLD50＜340mg/kg(rabbit)

sodiumsulfite（Na₂SO₃）

7757-83-7

AcuteOralLD50:3560mg/kg(rat)

sodiumthiosulfate（Na₂S₂O₃）

7772-98-7

AcuteOralLD50＞5000mg/kg(rat)

sodiumcarbonate（Na₂CO₃）

497-19-8

AcuteOralLD50:4090mg/kg(rat)

AcuteOralLD50:6600mg/kg(mouse)

.ContactwithEyes: Itcancausesevereeyeirritationandsymptomsmayincluderedness,tearandache..ContactwithSkin: Itcancauseirritationtoskinandsymptomsmayincluderednessandache.Inhalation:Nohazardfornormalconditions.Itmaycauseirritationtorespiratorysystemifinhalingdustorpowderfothisproduct.Symptomsmayincludecoughing,dizziness,drowsinessandtightnessinchest..Ingestion:Harmfulbyingestion.Itcancauseburnstointestinaltract.Symptomsmayincludenausea,vomitingand bellyache.

.EffectsofOverexposure–Chronic: Long-termorrepeatedexposuremaypoisoningasitmayreleasehydrogensulfideifcontactingcarbondioxide..Carcinogenicity:NotlistedbyIARC,NTP,ACGIHandEPA..Sensitivity:Notfound.Teratogenicity:Notfound..Mutagenicity:Notfound.

12.Ecologicalinformation

.Ecotoxicity:

Acutehazardstotheaquaticenvironment-1sodiumsulfide（Na₂S）（CAS:1313-82-2）LC50(freshwaterfish):700ug/L(96hours).PersistenceandDegradability:Thisproductisbiodegradable..BioaccumulativePotential:Notfound..MobilityinSoil:Ithardlymovesinsoilduetoitssolidnature.

.Notes:

Donotallowproducttoreachgroundwater,watercourseorsewagesystem.

13.Disposalconsiderations

Donotallowproducttoreachsewagesystem.Donotthrowitintoanyopenbodiesofwater.Wasterecyclingmustbeoperatedstrictlyaccordingtorelevantregulations.

14.TransportInformationDOT: .ProperShippingName: Sodiumsulfide,anhydrousorSodiumsulfidewithlessthan30percentwaterofcrystallization

.HazardClass:Class4.2.UNCode:UN1385.PackingGroup:Ⅱ

Air-Transportation-Air-Transportation-IATA/ICAO:

.ProperShippingName: Sodiumsulfide,anhydrousorSodiumsulfidewithlessthan30percentwaterofcrystallization

.HazardClass:Class4.2.UNCode:UN1385.PackingGroup:Ⅱ

Sea-Transportation-IMO/IMDG.:

.ProperShippingName: Sodiumsulfide,anhydrousorSodiumsulfidewithlessthan30percentwaterofcrystallization

.HazardClass:Class4.2.UNCode:UN1385.PackingGroup:Ⅱ

Note:Checkwhetherthepackageiscompletedorsealedbeforetransporting;makesuretherearenodamageandnofallingdownofpackagesduringtransporting;thetransportvehicleshouldbeequippedwithfire-fightingequipmentsandemergencyfacilitiesforhandlingwithrelease;doNOTtransportthisproducttogetherwithincompatiblesubstances.

15.Regulatoryinformation

.DomesticLawsandRegulations:

.Generalruleforclassificationandhazardcommunicationofchemicals(GB13690-2009):

Pyrophoricsolids-1;Acutetoxicity(oral)-4;Acutetoxicity(dermal)-4;Skincorrosion/irritation-2;

Seriouseyedamage/eyeirritation-2A; Acutehazardstotheaquaticenvironment-1.ThePrincipleofClassificationofTransportPackagingGroupsofDangerousGoods(GB/T15098-2008):

Ⅱ.DangerousChemicalsList(GB12268):

UN1835,Sodiumsulfide,anhydrousorSodiumsulfidewithlessthan30percentwaterofcrystallization,packinggroup:Ⅱ,

class4.2

.InternationalLawsandRegulations:

.TSCA(ToxicSubstanceControlAct): Sodiumsulfide（Na₂S）(CAS:1313-82-2),sodiumsulfite（Na₂SO₃）(CAS:7757-83-7), sodiumthiosulfate（Na₂S₂O₃）(CAS:7772-98-), sodiumcarbonate（Na₂CO₃）（CAS:497-19-8）andiron（Fe）(CAS: 7439-89-6)areontheU.S.ToxicSubstancesControlActChemicalSubstanceInventoryList..67/548/EECAnnexⅢandAnnexⅣ：

Ingredient(s)

RiskPhrase

SafetyPhrase

Sodiumsulfide（Na₂S）（CAS：1313-82-2）

R22-24-31-34-50

S(1/2-)26-36/37/39-45-61

sodiumcarbonate（Na₂CO₃）

R36

S(2-)22-26

.Carcinogenicitycategories:NotlistedbyEPA,IARCandNTP.

16.Otherinformation

References：

GB15258-2009GB16483-2008GHSAnnexⅡGHSSDSInstruction

Fulldescriptionofsomeacronyms:

GHS-GloballyHarmonizedSystemofClassificationandLabellingofChemicals

CAS-ChemicalAbstractsService

EINECS-EuropeanInventoryofExistingCommercialChemicalSubstancesIMO-InternationalMaritimeOrganizationIMDG-InternationalMaritimeDangerousGoodsIATA-InternationalAirTransportAssociationICAO-InternationalCivilAviationOrganization

TSCA-ToxicSubstanceControlAct

OSHA-OccupationalSafetyandHealthAdministration

ACGIH- AmericanConferenceofGovernmentalIndustrialHygienists

FulldescriptionofRiskPhraseandSafetyPhraselistedinSection15:

R22:Harmfulifswallowed.R24:Toxicincontactwithskin.R31:Contactwithacidsliberatestoxicgas.R34:Causesburns.R36:Irritatingtoeyes.R50:Verytoxictoaquaticorganisms.S2:Keepoutofthereachofchildren.S22:Donotbreathedust.S26:Incaseofcontactwitheyes,rinseimmediatelywithplentyofwaterandseekmedicaladvice.S36:Wearsuitableprotectiveclothing.S37:Wearsuitablegloves.S39:Weareye/faceprotection.S45:Incaseofaccidentorifyoufeelunwellseekmedicaladviceimmediately(showthelabelwherepossible).S61:Avoidreleasetotheenvironment.Refertospecialinstructions/safetydatasheet.

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