英文SDS报告是什么样的符合GHS标准的化学品安全技术说明书样例_MSDS|MSDS报告|MSDS是什么意思|MSDS证书|MSDS认证|MSDS翻译|MSDS编制|MSDS查询

Safety Data Sheet

The content and format of this SDS is accordant with GHS standard.

1. Identification of the substance/preparation and of the company/undertaking

.Product name : Anhydrous sodium sulfide

.Application of the substance: Applied in manufacturing of PPS, pharmaceutical intermediates, cosmetic intermediates and food additives. It also can be used in scientific experiment. Do NOT use it in a way which may contaminate food or do harm to human health.

.Manufacturer/Supplier:

.Address:

Tel:

Fax:

.Further information obtainable from:

.Information in case of emergency:

2. Hazards identification

.GHS classification according to Annex Ⅱ:

Physical hazards	Health hazards	Environmental hazards
Explosives-not classified Flammable gases-not classified Flammable aerosols-not classified Gases under pressure- not classified Flammable liquids- not classified Flammable solids-not classified Self-reactive substances and mixtures-not classified Pyrophoric liquids-not classified Pyrophoric solids-1 Self-heating substances and mixtures-not classified Substances and mixtures, which in contact with water, emit flammable gases-not classified Oxidizing liquids-not classified Oxidizing solids-not classified Organic peroxides-not classified Corrosive to metals-not classified	Acute toxicity (oral)-4 Acute toxicity (dermal)-4 Acute toxicity (inhalation)- not classified Skin corrosion/irritation-2 Serious eye damage/eye irritation-2A Respiratory sensitizer-not classified Skin sensitizer- not classified Germ cell mutagenicity-not classified Carcinogenicity-not classified Toxic to reproduction- not classified Effects on or via lactation-not classified STOT SE- not classified STOT RE- not classified	Acute hazards to the aquatic environment-1 Chronic hazards to the aquatic environment- not classified

.Signal word: Danger

.Symbol :

.Hazard Statement:

H250: Catches fire spontaneously if exposed to air.

H302: Harmful if swallowed.

H312: Harmful in contact with skin.

H315:Causes skin irritation.

H319: Causes serious eye irritation.

H400: Very toxic to aquatic life.

.Precautionary Statements:

P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.

P222: Do not allow contact with air.

P264: Wash hands thoroughly after handling.

P270 : Do not eat, drink or smoke when using this product.

P272: Contaminated work clothing should not be allowed out of the workplace.

P280 : Wear protective gloves (e.g. acid and alkali resistant gloves) /protective clothing (e.g. antistatic protective clothing)

/eye protection/face protection.

P273 : Avoid release to the environment.

.Response Precautionary Statements:

P335+P334 : Brush off loose particles from skin.Immerse in cool water/wrap in wet bandages.

P332+P313 : If skin irritation occurs: Get medical advice/attention.

P362 : Take off contaminated clothing and wash before reuse.

P305 + P351 + P338+ P310: IF IN EYES: Remove contact lenses if present and easy to do. continue rinsing. Immediately get medical advice/attention.

P301+330+331+310 : IF SWALLOWED : Rinse mouth immediately. Do NOT induce vomiting, get medical attention immediately.

P304+P312 : IF INHALED : Call a POISON CENTER or doctor/physician if you feel unwell.

P378: Use proper extinguishers for extinction (e.g. loess, sand, tap water, etc.).

.Storage precautionary statements :

P401: Store in a closed container without exposure to air. Do NOT store together with acids or oxidants.

.Disposal precautionary statements :

P501: Dispose of contents/container to relevant local and national regulations.

3. Composition/information on ingredients

Product description: substance (); preparation/mixture (√)

Ingredients	CAS	EINECS	% by weight
Ingredients	CAS	EINECS	% by weight	sodium sulfide（Na₂S）	1313-82-2	215-211-5	≥92%
sodium sulfite（Na₂SO₃）	7757-83-7	231-821-4	≤0.8%
sodium thiosulfate（Na₂S₂O₃）	7772-98-7	231-867-5	≤1.60%
sodium carbonate（Na₂CO₃）	497-19-8	207-838-8	≤1.50%
impurity	--	--	≤0.050%
water（H₂O）	7732-18-5	--	≤4.10%
iron（Fe）	7439-89-6	--	0.0020%

4 First aid measures

Persons using this product should consult a physician or other medical professional if an accident involving this product in injury. Specific first-aid measures are as follows:

.Eyes Contact: Immediately raise eyelids and flush with plenty of water at least for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation persists, seek medical care.

.Skin Contact: Immediately water contaminated area with plenty of water and soap. Remove all contaminated clothing and wash thoroughly before reuse. If irritation persists, get medical attention.

.Inhalation: Remove to fresh air. Call a POISON CENTER or doctor/physician if you feel unwell.

.Ingestion: Do not induce vomiting without professional instruction. Get medical attention immediately.

.Acute effect and delayed effect: Acute effect: It causes irritation to skin and serious irritation to eyes. In case of ingestion, it

cause irritation to gastrointestinal tract. Delayed effect: Long-term or repeated exposure may poisoning as it may release

hydrogen sulfide if contacting carbon dioxide.

.Personal protective equipment : Wear protective gloves (e.g. acid and alkali resistant gloves). Wear respirators and safety

goggles when exposure limits are exceeded or working in a dusty environment.

5. Fire-fighting measures

.Flash point: Not available

.Flammable/Explosive Limits-Lower Vol %: Not available

.Flammable/Explosive Limits-Upper Vol %: Not available

.Extinguishing Media: Use loess or sand for small fire; use water for large fire. Do NOT us CO₂as extinguishing media. Seek advice from local fire-fighting authority.

.Fire Fighting Equipments: Firefighters must wear self-contained breathing apparatus and full protective equipment.

.Unusual Fire and Explosion Hazards: The mixture of air and the powder of this product is explosive. It can liberate hydrogen sulfide gases when reacting with acids. Hydrogen sulfide gas is toxic and flammable.

.Hazardous Combustion Products: It can liberate toxic and irritating fume from combustion (e.g. sulfur dioxide and hydrogen sulfide ).

6. Accidental release measures

.Personal precautions: Use proper personal protective equipment as indicated in Section 8.

.Measures for Cleaning/Collection:

Small Spill:

Sweep up carefully to avoid generating dust. Collect into bags and transfer to a safe place.

Large Spill:

Isolate contaminated area and set up a warning board. The persons handling emergency are recommended wearing protective mask and clothing. Do NOT touch spilled material.

Cover the spilled powder with plastic cloth or canvas. Try to recycle it.

.Environmental Precautions: Keep cleaning run-offs out of municipal sewers and open bodies of water. Comply with local and national laws and regulations.

7. Handling and storage

.Handling:

Do not breathe vapor that may be evolved during processing.

Workers must wear proper protective equipments and must operate strictly according to relative rules.

.Information about fire- and explosion protection:

Keep ignition sources away—Do not smoke.

.Storage:

.Requirements to be met by storerooms: Store it in a well-ventilated, cool and dry store room. Keep containers tightly sealed. Do NOT store together with acids or oxidants.

.Additional Information: The storeroom should be equipped with proper facilities for accidental leakage and fire.

8. Exposure controls/personal protection

Ingredients	OSHA PEL-TWA	ACGIH TLV-TWA
Ingredients	OSHA PEL-TWA	ACGIH TLV-TWA	sodium sulfide（Na₂S）（CAS: 1313-82-2）	No available	No available
sodium sulfite（Na₂SO₃）（CAS: 7757-83-7）	No available	No available
sodium thiosulfate（Na₂S₂O₃）（CAS: 7772-98-7）	No available	No available
sodium carbonate（Na₂CO₃）（CAS: 497-19-8）	No available	No available
iron（Fe）（CAS : 7439-89-6）	No available	5mg/m³(iron oxides, fume and dust)

.Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust or fume, use ventilation to keep exposure to airborne contaminants below the exposure limit.

.Personal Protective Equipments:

.Protection of Hands:

Wear acid and alkali resistant gloves.

.Protection of Eyes:

No special requirements under normal conditions. Wear safety glasses when dust or fume may contact eyes.

.Respiratory Protection: Use an approved respirator (e.g. self-inhalation filter-type dust respirator) if exposure limits are exceeded or if irritation or other symptoms occur.

.Protection of Body:

Wear acid and alkali resistant uniforms.

.General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.

Wash hands before breaks and at the end of work.

Avoid contact with eyes and skin.

9. Physical and chemical properties

General Information
Form	Granules (solid)
Color	Light yellow
Odor	Slightly smelly
Boiling Range	Not available
Melting point/Melting range	1180℃(Na₂S)
Flash point	Not available
Self-igniting	Not available
Flammable/Explosive Limits-Lower Vol %	Not available
Flammable/Explosive Limits-Upper Vol %	Not available
Density（@15℃）	Approx. 1.856
Relative Vapor density	Not available
Vapor pressure	Not available
Solubility in/Miscibility with Water	Soluble in water
PH-Value	Not available
Viscosity (cSt@100℃)	Not available

10. Stability and reactivity

.Chemical Stability: Stable under normal temperatures and pressures.

.Hazardous Decomposition Products: It can liberate toxic and irritating fume from combustion.

.Materials to avoid: Acids and strong oxidants.

.Hazardous Polymerizations: Will not occur.

.Conditions to Avoid: Light, long-time exposure to air and moisture.

11. Toxicological information

.Product Toxicity Data: The toxicity data of this product has not been determined by testing or research, but to relevant literature and classification standard in Annex 2 of GHS, this product is toxic. The toxicity data shown below is for reference only.

Ingredients	CAS	LD 50/ LC 50
sodium sulfide（Na₂S）	1313-82-2	Acute Oral LD50: 300mg/kg (rat) Acute Dermal LD50＜340mg/kg (rabbit)
sodium sulfite（Na₂SO₃）	7757-83-7	Acute Oral LD50: 3560mg/kg (rat)
sodium thiosulfate（Na₂S₂O₃）	7772-98-7	Acute Oral LD50＞5000mg/kg (rat)
sodium carbonate（Na₂CO₃）	497-19-8	Acute Oral LD50: 4090mg/kg (rat) Acute Oral LD50: 6600mg/kg (mouse)

.Contact with Eyes: It can cause severe eye irritation and symptoms may include redness, tear and ache.

.Contact with Skin: It can cause irritation to skin and symptoms may include redness and ache

.Inhalation: No hazard for normal conditions. It may cause irritation to respiratory system if inhaling dust or powder fo this product. Symptoms may include coughing, dizziness, drowsiness and tightness in chest.

.Ingestion: Harmful by ingestion. It can cause burns to intestinal tract. Symptoms may include nausea, vomiting and bellyache.

.Effects of Overexposure – Chronic: Long-term or repeated exposure may poisoning as it may release hydrogen sulfide if

contacting carbon dioxide.

.Carcinogenicity: Not listed by IARC, NTP, ACGIH and EPA.

.Sensitivity: Not found

.Teratogenicity: Not found.

.Mutagenicity: Not found.

12. Ecological information

.Ecotoxicity:

Acute hazards to the aquatic environment-1

sodium sulfide（Na₂S）（CAS: 1313-82-2）

LC50 (freshwater fish): 700ug/L (96 hours)

.Persistence and Degradability: This product is biodegradable.

.Bioaccumulative Potential: Not found.

.Mobility in Soil: It hardly moves in soil due to its solid nature.

.Notes:

Do not allow product to reach ground water, water course or sewage system.

13. Disposal considerations

Do not allow product to reach sewage system.

Do not throw it into any open bodies of water.

Waste recycling must be operated strictly according to relevant regulations.

14. Transport Information

DOT:

.Proper Shipping Name: Sodium sulfide, anhydrous or Sodium sulfide with less than 30 percent water of crystallization

.Hazard Class: Class 4.2

.UN Code: UN 1385

.Packing Group: Ⅱ

Air-Transportation- Air-Transportation- IATA/ICAO:

.Proper Shipping Name: Sodium sulfide, anhydrous or Sodium sulfide with less than 30 percent water of crystallization

.Hazard Class: Class 4.2

.UN Code: UN 1385

.Packing Group: Ⅱ

Sea-Transportation-IMO/IMDG.:

.Proper Shipping Name: Sodium sulfide, anhydrous or Sodium sulfide with less than 30 percent water of crystallization

.Hazard Class: Class 4.2

.UN Code: UN 1385

.Packing Group: Ⅱ

Note:

Check whether the package is completed or sealed before transporting; make sure there are no damage and no falling down of packages during transporting; the transport vehicle should be equipped with fire-fighting equipments and emergency facilities for handling with release; do NOT transport this product together with incompatible substances.

15. Regulatory information

.Domestic Laws and Regulations:

.General rule for classification and hazard communication of chemicals(GB 13690-2009):

Pyrophoric solids-1; Acute toxicity (oral)-4; Acute toxicity (dermal)-4; Skin corrosion/irritation-2;

Serious eye damage/eye irritation-2A; Acute hazards to the aquatic environment-1

.The Principle of Classification of Transport Packaging Groups of Dangerous Goods (GB/T 15098-2008):

Ⅱ

.Dangerous Chemicals List (GB 12268):

UN1835, Sodium sulfide, anhydrous or Sodium sulfide with less than 30 percent water of crystallization, packing group:Ⅱ,

class 4.2

.International Laws and Regulations:

.TSCA (Toxic Substance Control Act): Sodium sulfide（Na₂S）(CAS: 1313-82-2), sodium sulfite（Na₂SO₃）(CAS: 7757-83-7), sodium thiosulfate（Na₂S₂O₃）(CAS: 7772-98-), sodium carbonate（Na₂CO₃）（CAS: 497-19-8）and iron（Fe）(CAS : 7439-89-6) are on the U.S. Toxic Substances Control Act Chemical Substance Inventory List.

. 67/548/EECAnnex Ⅲ and Annex Ⅳ：

Ingredient (s)	Risk Phrase	Safety Phrase
Sodium sulfide（Na₂S）（CAS：1313-82-2）	R22-24-31-34-50	S(1/2-)26-36/37/39-45-61
sodium carbonate（Na₂CO₃）	R36	S(2-)22-26

.Carcinogenicity categories: Not listed by EPA, IARC and NTP.

16. Other information

References：

GB 15258-2009

GB 16483-2008

GHS AnnexⅡ

GHS SDS Instruction

Full description of some acronyms:

GHS-Globally Harmonized System of Classification and Labelling of Chemicals

CAS-Chemical Abstracts Service

EINECS-European Inventory of Existing Commercial Chemical Substances

IMO-International Maritime Organization

IMDG-International Maritime Dangerous Goods

IATA-International Air Transport Association

ICAO-International Civil Aviation Organization

TSCA-Toxic Substance Control Act

OSHA-Occupational Safety and Health Administration

ACGIH- American Conference of Governmental Industrial Hygienists

Full description of Risk Phrase and Safety Phrase listed in Section 15:

R22: Harmful if swallowed.

R24: Toxic in contact with skin.

R31: Contact with acids liberates toxic gas.

R34: Causes burns.

R36: Irritating to eyes.

R50: Very toxic to aquatic organisms.

S2: Keep out of the reach of children.

S22: Do not breathe dust.

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36: Wear suitable protective clothing.

S37: Wear suitable gloves.

S39: Wear eye/face protection.

S45: In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

S61: Avoid release to the environment. Refer to special instructions/safety data sheet.

The latest version issuing date:

SDS Version:

********************************The End *******************************

搜索

热门标签:

英文SDS报告是什么样的符合GHS标准的化学品安全技术说明书样例