Section4-FIRSTAIDMEASURES

Generalinformation

Immediatelyremoveanyclothingsoiledbytheproduct.
Removebreathingapparatusonlyaftercontaminatedclothinghasbeencompletelyremoved.
Incaseofirregularbreathingorrespiratoryarrestprovideartificial
respiration.
 

Afterinhalation

Supplyfreshair.Ifrequired,provideartificialrespiration.Keep
patientwarm.
Seekimmediatemedicaladvice.
 

Afterskincontact

Immediatelywashwithwaterandsoapandrinsethoroughly.
Seekimmediatemedicaladvice.
 

Aftereyecontact

Rinseopenedeyeforseveralminutesunderrunningwater.Thenconsulta
doctor.
 

Afterswallowing

Donotinducevomiting;immediatelycallformedicalhelp.
Seekimmediatemedicaladvice.
 

Informationfordoctor

Thefollowingsymptomsmayoccur:

Nausea
Headache
Gastricorintestinaldisorders.
Dizziness
Unconsciousness

Section5-FIREFIGHTINGMEASURES

Suitableextinguishingagents

Carbondioxide,extinguishingpowderorwaterspray.Fightlargerfires
withwatersprayoralcoholresistantfoam.
 

Specialhazardscausedbythematerial,itsproductsofcombustionor

resultinggases:

Incaseoffire,thefollowingcanbereleased:
Carbonmonoxideandcarbondioxide
 

Protectiveequipment:

Wearself-containedrespirator.
Wearfullyprotectiveimpervioussuit.

Section6-ACCIDENTALRELEASEMEASURES

Person-relatedsafetyprecautions:

Wearprotectiveequipment.Keepunprotectedpersonsaway.
Ensureadequateventilation
Keepawayfromignitionsources
 

Measuresforenvironmentalprotection:

Donotallowmaterialtobereleasedtotheenvironmentwithoutproper
governmentalpermits.
 

Measuresforcleaning/collecting:

Absorbwithliquid-bindingmaterial(sand,diatomite,acidbinders,
universalbinders,sawdust).
Disposecontaminatedmaterialaswasteaccordingtoitem13.
Ensureadequateventilation.
Keepawayfromignitionsources.
 

Additionalinformation:

SeeSection7forinformationonsafehandling
SeeSection8forinformationonpersonalprotectionequipment.
SeeSection13fordisposalinformation.

Section7-HANDLINGANDSTORAGE

Handling

Informationforsafehandling:

Keepcontainertightlysealed.
Storeincool,dryplaceintightlyclosedcontainers.
Ensuregoodventilationattheworkplace.
Openandhandlecontainerwithcare.
 

Informationaboutprotectionagainstexplosionsandfires:

Keepignitionsourcesaway.
Protectagainstelectrostaticcharges.
Fumescancombinewithairtoformanexplosivemixture.
 

Storage

Requirementstobemetbystoreroomsandreceptacles:

Storeinacoollocation.
 

Informationaboutstorageinonecommonstoragefacility:

Donotstoretogetherwithoxidizingandacidicmaterials.
Donotstoretogetherwithalkalies(causticsolutions).
Storeawayfromhalogens.
 

Furtherinformationaboutstorageconditions:

Keepcontainertightlysealed.
Storeincool,dryconditionsinwellsealedcontainers.

Section8-EXPOSURECONTROLS/PERSONALPROTECTION

Additionalinformationaboutdesignoftechnicalsystems:

Properlyoperatingchemicalfumehooddesignedforhazardouschemicals
andhavinganaveragefacevelocityofatleast100feetperminute.
 

Componentswithlimitvaluesthatrequiremonitoringattheworkplace:

Ethylalcohol                 ppm
ACGIHTLV                   1000-STEL;Confirmedanimalcarcinogenwithunknown
relevancetohumans.
AustriaMAK                1000
BelgiumTWA               1000
DenmarkTWA              1000
FinlandTWA                1000;1250-STEL
FranceVME                  1000;5000-VLE
GermanyMAK               1000
KoreaTLV                     1000
NetherlandsMAC-TGG    500
NorwayTWA                  500
PolandTWA                 1000mg/m3;3000mg/m3-STEL
Russia                          1000mg/m3-STEL
SwedenNGV                 500;1000-KTV
SwitzerlandMAK-W       1000
UnitedKingdomTWA      1000
OSHAPEL                     1000
Methylalcohol                    ppm
ACGIHTLV                     200;250-STEL(skin)
AustriaMAK                   200(skin)
BelgiumTWA                 200;250-STEL,(skin)
DenmarkTWA                200(skin)
FinlandTWA                  200;250-STEL(skin)
FranceVME                   200;1000-VLE
HungaryTWA                50mg/m3;100mg/m3-STEL(skin)
JapanOEL                     200(skin)
KoreaTLV                     200;250-STEL(skin)
NetherlandsMAC-TGG   200(skin)
NorwayTWA                 100
PolandTWA                 100mg/m3;300mg/m3-STEL
RussiaTWA                  200;5mg/m3-STEL(skin)
SwedenNGV                 200;250-KTV(skin)
UnitedKingdomTWA     200;250-STEL(skin)
OSHAPEL                    200
Isopropylalcohol(2-Propanol)   ppm
ACGIHTLV                   400;500-STEL
AustriaMAK                  400
BelgiumTWA                 400;500-STEL
DenmarkTWA                200
FranceVLE                    400
GermanyMAK                400
IrelandTWA                    400;500-STEL(skin)
JapanTWA                     400-STEL
KoreaTWA                     400;500-STEL
NetherlandsMAC-TGG     400(skin)
NorwayTWA                   100
PolandTWA                    900;1200-STEL
RussiaTWA                    400-STEL
SwedenNGV                  150;250-STEL
SwitzerlandMAK-W         400
UnitedKingdomTWA       400;500-STEL
OSHAPEL                     400
 

Additionalinformation:

Nodata
 

Personalprotectiveequipment

Generalprotectiveandhygienicmeasures

Theusualprecautionarymeasuresforhandlingchemicalsshouldbe
followed.
Keepawayfromfoodstuffs,beveragesandfeed.
Removeallsoiledandcontaminatedclothingimmediately.
Washhandsbeforebreaksandattheendofwork.
Storeprotectiveclothingseparately.
 

Breathingequipment:
Usesuitablerespiratorwhenhighconcentrationsarepresent.

Protectionofhands:

Imperviousgloves
 

Eyeprotection:

Safetyglasses
 

Bodyprotection:

Protectiveworkclothing.

Section9-PHYSICALANDCHEMICALPROPERTIES

GeneralInformation Form:                                                                             Liquid
Color:                                                                            Colorless
Odor:                                                                            Alcohol-likeChangeincondition
Meltingpoint/Meltingrange:                                -114°C(-173°F)
Boilingpoint/Boilingrange:                                    78°C(172°F)
Sublimationtemperature/start:                         NotdeterminedFlashpoint:                                                                8°C(46°F)Ignitiontemperature:                                             362°C(684°F)Decompositiontemperature:                              NotdeterminedExplosionlimits:
Lower:                                                                         3.3Vol%
Upper:                                                                         19.0Vol%Vaporpressureat20°C(68°F):                            58.5hPa(44mmHg)Densityat20°C(68°F):                                            0.79g/cm3Solubilityin/Miscibilitywith
Water:                                                                          Fullymiscible
Alcohols:                                                                     Soluble

Section10-CHEMICALSTABILITYANDREACTIVITYINFORMATION

Thermaldecomposition/conditionstobeavoided:
Decompositionwillnotoccurifusedandstoredaccordingto
specifications.
Materialstobeavoided:
Halogens
Oxidizingagents
Bases
Acidchlorides
Acidanhydrides
Alkalimetals
Dangerousreactions                                           Reactswithoxidizingagents
Dangerousproductsofdecomposition:             Carbonmonoxideandcarbondioxid

Section11-TOXICOLOGICALINFORMATION

Acutetoxicity:
LD/LC50valuesthatarerelevantforclassification:
ORL-RATLD50:7060MG/KG(ETHANOL)
ORL-MUSLD50:3450MG/KG(ETHANOL)
IHL-RATLC50:20000PPM/10H(ETHANOL)
ORL-RATLD50:5628MG/KG(METHANOL)
ORL-MUSLD50:7300MG/KG(METHANOL)
SKN-RBTLD50:15800MG/KG(METHANOL)
ORL-HMNLDLo:143MG/KG(METHANOL)
ORL-RATLD50:5045MG/KG(ISOPROPANOL)
ORL-MUSLD50:3600MG/KG(ISOPROPANOL)
SKN-RBTLD50:12800MG/KG(ISOPROPANOL)
ORL-HMNLD50:3570MG/KG(ISOPROPANOL)