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Risk-Phrases(危险警语)和Safety Phrases(安全警语)的详细诠释

在MSDS中,我们经常会看到危险警语和安全警语,该警语由欧盟指令67/548/EEC附录Ⅲ 制定。具体描述如下:

 


 
危险警语R-phrases:
   R1          Explosive when dry. 干燥时易爆。
 R2          Risk of explosion by shock, friction, fire or other source of ignition. 受冲击、摩擦、着火或其他引燃源有爆炸危险。
 R3          Extreme risk of explosion by shock, friction, fire or other sources of ignition.
 受冲击、摩擦、着火或其他引燃源有极高爆炸危险。
 R4          Forms very sensitive explosive metallic compounds. 生成极敏感的爆炸性金属化合物。
 R5          Heating may cause an explosion. 受热可能引起爆炸。
 R6          Explosive with or without contact with air.极容易爆炸。
 R7          May cause fire. 可能引起火灾。
 R8          Contact with combustible material may cause fire. 与可燃物料接触可能引起火灾。
 R9          Explosive when mixed with combustible material. 与可燃物料混合有爆炸性。
 R10          Flammable. 易燃。
 R11          Highly flammable. 高度易燃。
 R12          Extremely flammable. 极度易燃。
 R13          Extremely flammable liquefied gas 极度易燃的液化气体。
 R14          Reacts violently with water. 遇水反应剧烈。
 R15          Contact with water liberates extremely flammable gases. 遇水释放极易燃烧的气体。
 R16          Explosive when mixed with oxidizing substances. 与氧化性物质混合有爆炸性。
 R17          Spontaneously flammable in air. 在空气中可自燃。
 R18          In use, may form inflammable/explosive vapour-air mixture. 使用时可能产生易燃易爆的蒸汽-空气混合物。
 R19          May form explosive peroxides. 可能生成爆炸性过氧化物。
 R20          Harmful by inhalation. 吸入有害。
 R21          Harmful in contact with skin. 与皮肤接触有害。
 R22          Harmful if swallowed. 吞食有害。
 R23          Toxic by inhalation. 吸入有毒。
 R24          Toxic in contact with skin. 与皮肤接触有毒。
 R25          Toxic if swallowed. 吞食有毒。
 R26          Very toxic by inhalation. 吸入有极高毒性。
 R27          Very toxic in contact with skin. 与皮肤接触有极高毒性。
 R28          Very toxic if swallowed. 吞食有极高毒性。
 R29          Contact with water liberates toxic gas. 遇水释放有毒气体。
 R30          Can become highly flammable in use. 使用中高度易燃。
 R31          Contact with acids liberates toxic gas. 遇酸释放有毒气体。
 R32          Contact with acid liberates very toxic gas. 与酸接触释放极高毒性气体。
 R33          Danger of cumulative effects. 有累积效应的危险品。
 R34          Causes burns. 引起灼伤。
 R35          Causes severe burns. 引起严重灼伤。
 R36          Irritating to eyes. 刺激眼睛。
 R37          Irritating to respiratory system. 刺激呼吸系统。
 R38          Irritating to skin. 刺激皮肤。
 R39          Danger of very serious irreversible effects. 有极严重的不可逆后果的危险品。
 R40          Limited evidence of a carcinogenic effect. 少数报道有致癌后果。
 R41          Risk of serious damage to the eyes. 对眼睛有严重伤害。
 R42          May cause sensitization by inhalation. 吸入可能致敏。
 R43          May cause sensitization by skin contact. 与皮肤接触可能致敏。
 R44          Risk of explosion if heated under confinement. 密闭加热有爆炸危险。
 R45          May cause cancer. 可能致癌。
 R46          May cause heritable genetic damage. 可能引起遗传性基因损害。
 R47          May cause birth defects 可能引起胎儿缺陷。
 R48          Danger of serious damage to health by prolonged exposure. 长期接触严重危害健康。
 R49          May cause cancer by inhalation. 吸入可能致癌。
 R50          Very toxic to aquatic organisms. 对水生生物有极高毒性。
 R51          Toxic to aquatic organisms. 对水生生物有毒。
 R52          Harmful to aquatic organisms. 对水生生物有害。
 R53          May cause long-term adverse effects in the aquatic environment. 可能对水体环境产生长期不良影响。
 R54          Toxic to flora. 对植物有毒。
 R55          Toxic to fauna. 对动物有毒。
 R56          Toxic to soil organisms. 对土壤生物有毒。
 R57          Toxic to bees. 对蜂类有毒。
 R58          May cause long-term adverse effects in the environment. 可能对环境产生长期不良影响。
 R59          Dangerous to the ozone layer. 对臭氧层有危害。
 R60          May impair fertility. 可能损害生育能力。
 R61          May cause harm to the unborn child. 可能对胎儿造成伤害。
 R62          Risk of impaired fertility. 有损害生育能力的危险。
 R63          Possible risk of harm to the unborn child. 可能有对胎儿造成伤害的危险。
 R64          May cause harm to breastfed babies. 可能对哺乳期婴儿造成伤害。
 R65          Harmful: may cause lung damage if swallowed. 吞食可能造成肺部损伤。
 R66          Repeated exposure may cause skin dryness or cracking. 长期接触可能引起皮肤干裂。
 R67          Vapours may cause drowsiness and dizziness. 蒸汽可能引起困倦和眩晕。
 R68          Possible risk of irreversible effects. 可能有不可逆后果的危险。
 R20/21:          Harmful by inhalation and in contact with skin. 吸入及皮肤接触有害。
 R20/21/22:         Harmful by inhalation, in contact with skin and if swallowed. 吸入、皮肤接触及吞食有害。
 R20/22:         Harmful by inhalation and if swallowed. 吸入及吞食有害。
 R21/22:         Harmful in contact with skin and if swallowed. 皮肤接触及吞食有害。
 R23/24/25:         Toxic by inhalation, in contact with skin and if swallowed. 吸入、皮肤接触及吞食有毒。
 R23/25:         Toxic by inhalation and if swallowed. 吸入及吞食有毒。
 R26/27/28:         Very toxic by inhalation, in contact with skin and if swallowed. 吸入、皮肤接触及吞食有极高毒性。
 R26/28:         Very toxic by inhalation and if swallowed. 吸入及吞食有极高毒性。
 R36/37:         Irritating to eyes and respiratory system. 刺激眼睛和呼吸系统。
 R36/37/38:          Irritating to eyes, respiratory system and skin. 刺激眼睛、呼吸系统和皮肤。
 R37/38:          Irritating to eyes and skin. 刺激眼睛和皮肤。
 R37/38:          Irritating to respiratory system and skin. 刺激呼吸系统和皮肤。
 R42/43:         May cause sensitization by inhalation and skin contact. 吸入及皮肤接触可能致敏。
 R48/22:         Harmful: danger of serious damage to health by prolonged exposure if swallowed. 吞食长期接触严重危害健康。
 R50/53:          Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
 对水生生物有极高毒性,可能对水体环境产生长期不良影响。
 R51/53:          Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
 对水生生物有毒,可能对水体环境产生长期不良影响。
 R52/53:            Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
 对水生生物有害,可能对水体环境产生长期不良影响。
 
安全警语S-phrases:
  • (S1): Keep locked up 保持封闭
  • (S2): Keep out of the reach of children存放在儿童接触不到的地方
  • S3: Keep in a cool place 存放在凉爽的地方
  • S4: Keep away from living quarters 存放在远离居住区的地方
  • S5: Keep contents under ... (appropriate liquid to be specified by the manufacturer)保存在…中(可由厂家建议一种合适的液体)
  • S6: Keep under ... (inert gas to be specified by the manufacturer)保存在…(可由厂家建议一种合适的惰性气体)
  • S7: Keep container tightly closed 保持容器紧密封闭
  • S8: Keep container dry 保持容器干燥
  • S9: Keep container in a well-ventilated place 将容器安置于通风良好处
  • S10: Keep contents wet 保持物质的湿度
  • S11: Avoid contact with air 避免接触空气
  • S12: Do not keep the container sealed 不要将容器封死
  • S13: Keep away from food, drink and animal foodstuffs 远离食品,饮料和动物饲料
  • S14: Keep away from ... (incompatible materials to be indicated by the manufacturer) 远离…(可由厂家列出不相容物质)
  • S15: Keep away from heat 远离热源
  • S16: Keep away from sources of ignition - No smoking 远离火源-禁止吸烟
  • S17: Keep away from combustible material 远离可燃物质
  • S18: Handle and open container with care 搬运及打开容器时要当心
  • S20: When using do not eat or drink 使用时,不得同时饮食
  • S21: When using do not smoke 使用时,不得吸烟
  • S22: Do not breathe dust 避免吸入粉尘
  • S23: Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 避免吸入气体/烟雾/蒸汽/水雾(可由厂家给出具体的措词)
  • S24: Avoid contact with skin 避免接触皮肤
  • S25: Avoid contact with eyes 避免接触眼睛
  • S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 万一接触眼睛,立即使用大量清水冲洗并送医诊治
  • S27: Take off immediately all contaminated clothing 立即脱去被污染衣物
  • S28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 接触皮肤后,立即使用大量…清洗(具体的清洁剂可由厂家建议)
  • S29: Do not empty into drains 不要将残余物倒入排水沟
  • S30: Never add water to this product 千万不要可将水加入此产品
  • S33: Take precautionary measures against static discharges采取预防措施防止静电释放
  • S35: This material and its container must be disposed of in a safe way 该物质及容器必须采取安全的方式处置
  • S36: Wear suitable protective clothing 穿戴合适的防护服
  • S37: Wear suitable gloves 佩戴合适的手套
  • S38: In case of insufficient ventilation wear suitable respiratory equipment 在通风不良的场所,佩戴合适的呼吸设备
  • S39: Wear eye/face protection 佩戴眼/面防护设备
  • S40: To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer) 使用…(可由厂家建议合适的清洁剂)清洗被该物质污染的地面及所有物体
  • S41: In case of fire and/or explosion do not breathe fumes 当发生火灾和/或爆炸时,避免吸入烟雾
  • S42: During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer) 灭火时佩戴合适的呼吸设备(可由厂家给出合适的措词)
  • S43: In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water) 灭火时,使用…(加入注水不适合灭火,请注明合适的其它灭火剂,并写明——请勿使用注水)
  • S45: In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 出现意外或者感到不适,立即就医(最好带去产品容器标签)
  • S46: If swallowed, seek medical advice immediately and show this container or label 万一不慎吞咽,立刻寻求医生的建议(展示产品容器或者标签)
  • S47: Keep at temperature not exceeding ... °C (to be specified by the manufacturer) 保持温度不要超过…(可由厂家决定合适的温度)
  • S48: Keep wet with ... (appropriate material to be specified by the manufacturer) 使用…(可由厂家建议合适的物质)保持其湿润
  • S49: Keep only in the original container 只能保持在原来的容器当中
  • S50: Do not mix with ... (to be specified by the manufacturer) 不要与…(可由厂家给出建议)混合
  • S51: Use only in well-ventilated areas 只能在通风良好处使用
  • S52: Not recommended for interior use on large surface areas 不建议在大面积内部空间使用
  • S53: Avoid exposure - obtain special instructions before use 避免暴露-使用前先阅读专门的说明
  • S56: Dispose of this material and its container at hazardous or special waste collection point 在专门指定的废弃物收集点丢弃该残余物及包装容器
  • S57: Use appropriate containment to avoid environmental contamination 使用合适容器避免环境被污染
  • S59: Refer to manufacturer/supplier for information on recovery/recycling 回收时参考生产商和供应商提供的信息
  • S60: This material and its container must be disposed of as hazardous waste 该物质残余物和容器必须作为危险废弃物处理
  • S61: Avoid release to the environment. Refer to special instructions/safety data sheet 请勿排放到环境中。参考专门的说明/安全说明书
  • S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label 如果不慎吞咽,请勿催吐; 立刻就医并出示产品容器或标签
  • S63: In case of accident by inhalation: remove casualty to fresh air and keep at rest 万一吸入引起不适,立即撤离至空气清新处,休息片刻
  • S64: If swallowed, rinse mouth with water (only if the person is conscious) 万一吞咽,(只要吞食者清醒)漱口

 

 

 

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