-SkinContact:Immediatelyflushcontaminatedskinwithplentyofsuds.Takeoffcontaminatedclothing.Getmedicalcareforobviousdiscomfort.
-EyesContact:Immediatelyraiseeyelidsandflushwithplentyofwater.Makesurethereisnoresidualintheeyes.Getmedicalcare.
-ProperFire-ExtinguishingAgents:Drypowder,carbondioxide,foamandwater(onlyeffectiveforextensivefire).
-HazardousCombustionProducts:Toxicgascanbereleasedfromcombustion.
-ProtectionforFire-Fighting:Wearprotectiveclothinganduseself-containedbreathingapparatus.
6.MeasuresforAccidentalRelease
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PersonalProtection:Wearproperprotectiveapparatus.Avoidinhalinghazardousgas.
7.HandingandStorage
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EnvironmentalProtectionandCleaningMethods:Preventpollutantsfromenteringsewerssurfacewater,groundwaterandsoil.Collecthazardousmaterialsintoacleancontainerforproperdisposal.Absorbresidualwithinertmaterials.Disposeaccordingtorelevantlocallawsandregulations.
Handling:Stayawayfromheatandfiresources.Nosmoking.Avoidinhalinghazardousgas.Avoideyesandskincontact.Takeprecautionstoavoidstaticelectricityreleasing.
Storage:Storeinacoolandwell-ventilatedplace.Donotstoretogetherwithperoxides.Takeeffectiveprecautionsforstaticelectricity.Thetimeforstoragewillbeshorterifthisproductisexposedtosunlightasitcontainsstyrene.Storeitinafullysealedcontainerandputitinacoolanddryplace.
8.ExposureControl/PersonalProtection
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ExposureLimitsforHazardousSubstancesinWorkingPlace:
HazardousIngredient TLV/PEL
1)Styrene TGG8uun107mg/m3(TheNetherlands,2000)
|
PersonalProtection:
-RespiratoryProtection:Uselocalexhaustoroperateinafumehoodtokeeptheexposurelimitsofhazardoussubstancesintherecommendedones.Useaprotectiverespiratortoprotectface.
-SkinandBodyProtection:Wearchemicalprotectiveclothingandchemicalprotectiveshoes.
-HandsProtection:Wearchemicalprotectivegloves.(e.g.Butylgloves,PVAgloves)
-EyesProtection:Wearsafetygoggleswithsideprotection.
9.PhysicalandChemicalProperties
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PhysicalState:Liquid
Color:Lightyellow
Odor:Characteristic
BoilingPoint:Min.145℃(293℉)(Styrene)
MeltingPoint:-30℃(-22.9℉)(Styrene)
BulkDensity:1.1g/cm3
VaporDensity:Max.3.6(air=1)(Styrene)
VaporPressure:Max.0.6KPa(4.5mmHg,20℃)(Styrene)
Solubility:Solubleincoldwater
n-octanol/WaterPartitionCoefficient:Notapplicable
PH:Notapplicable
FlashPoint:ClosedCup33℃(91.4℉)
Self-IgnitionTemperature:Min.490℃(914℉)(Styrene)
ExplosionLimitinAir:Max.1.1%-8%(Styrene)
Viscosity(23℃):>300mPa.s
10.ReactivityandStability
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Conditionstobeavoided:Extremeheatanddirectsunlight.
Materialstobeavoided:Donotmixwithperoxides.
HazardousDecompositionProducts:Notfound.
11.ToxicologicalInformation
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AcuteToxicologicalData
(LD50,LC50):AcuteOral:LD50: 316mg/kg(rat)(Styrene).
AcuteGasToxicologicalData(LC50):4000ppm4hours(rat)(styrene)
12.EcologicalInformation
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MobilityinSoil:Nodata.
Persistence/Degradability:Nodata.
PotentialBioaccumulation:Nodata.
EcologicalToxicity:Nodata.
13.DisposalConsideration
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DisposalMethod(includingresidualandcontaminatedpackage):Adoptincinerationwithstrictcontrol.Theemptycontainermaycontainsolventvapor.Stayawayfromfire.Takeprecautionsforexplosionandtoxicgasrelease.Transportthewastetoaqualifiedagencyforproperdisposal.
14.TransportationInformation
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InternationalTransportationRegulations:
-UNCode:1866
ADR/RIDLabel
-ProperShippingName:Resinsolution,flammable
-ADR/RIDClass:3
-PackingGroup:Ⅲ
-DangerousGoodsCertificateNo.:30-1866
IMDG
-ProperShippingName:Resinsolution,flammable
-IMDGClass:3.3
-IMDGCode:3379
-PackingGroup:Ⅲ
-MFAG:310
-EmS:3-05
OceanPollutants:YES
IATA-DGR
-ProperShippingName:Resinsolution,flammable
-UN/IDCode:1866
-IATA-DGRClass:3
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