原文:
MATERIAL SAFETY DATA SHEET
( NITROCELLULOSE)
1. Chemical Product and Company Identification.
MATERIAL NAME : NITROCELLULOSE
CAS NO : 9004-70-0
RTECS NO : QW 0975200
UN NO. : 2556
PRODUCT NAME : Nitrocotton, Peacock cylin.
Molecular formula : C6H7(OH)2 ONO2
Hazard classification : High Flammable material
Usage : paint, ink, manufacture of adhesives, cigarette filter, manicure, fluorescent, Surface disposal of artificial leather, magnetic tape etc
MANUFACTURER AND SUPPLIER INFORMAITON
MANUFACTURER : KOREA C & C CO., LTD.
ADDRESS : 821 YONGAMRI, BONGDONGYEP, WANJU, JUNBUK, KOREA
TEL : 063 260 2072
FAX : 0653 262 0021
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2. Composition / Information on Ingredients
INGREDIENTS :
NITROCELLULOSE (NITROCOTTON)
PERCENTAGE (%) : 70 %
ISOPROPYLALCOHOL (ISOPROPYNMALL)
CAS NO.: 67 – 63 - 0
PERCENTAGE (%) : 30 %
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3. Hazards Identification
NFPA RATINGS (0~4) : HEALTH = 0, FLAMMABILITY = 3, REACTIVITY = 3
OSHA : NOTHING
NTP : NOTHING
LARC : NOTHING
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4. First Aid Measures
Inhalation : Move to fresh air. Stop breathing, try artificial respiration, Seek medical attention.
Skin : Wash off with property remover, wash affected area with soap and water. Seek medical attention.
Eyes : In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
Ingestion : Do induce vomiting. Seek immediate medical attention.
▶ Emergency Procedures
Use suitable protective clothing/equipment.
Eliminate all sources.
Do not allow to enter water courses or drains.
Mop up small spill.
Use sand or earth to absorb spill for larger spillages.
Sweep up dispose in accordance with local regulations.
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5. Fire Fighting Measures
Fire classification OSHA : 1B
Flammable point : approximate 180 C
Extinguishing Media : water spray, dry chemical, carbon dioxide (co2), foam
Special Fire – fighting procedures : Wear self-contained breathing apparatus and protective clothing. Use water spray to keep fir-exposed containers cool. Water may be ineffective in fighting the fire.
Unusual fire and explosion hazards : Flammable. Vapors may cause a flash fire or ignite explosively. Vapors may travel considerable distance to a source of ignition and flash back. Prevent buildup of vapors or gases to explosive concentrations.
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6. Accidental Release Measures
Eliminate all ignition sources. Absorb spill with vermiculite or other inert material, then place in a container for chemical waste.
For large spills : Use water spray to disperse vapors and flush spill area. Prevent runoff from entering drains, sewers, or streams.
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7. Handling and Storage
Keep containers tightly closed. Keep containers cool, dry away from source of ignition
and store with adequate ventilation and follow regulation of 29 CFR 1910. 106. Avoid inhalation vapors. Use good personnel hygiene practice. Use a well ventilated area.
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8. Exposure controls / Personal Protection
Exposure standard (Isopropylalcohol)
Industrial safety health measures. : TWA (400 PPM), STEL (500 PPM)
OSHA PEL : TWA (400 PPM), STEL (500 PPM)
ACGIH TLV : TWA (400 PPM), STEL (500 PPM)
NIOSH REL : TWA (400 PPM), STEL (500 PPM)
Ventilation : Good general ventilation should be used. Ventilation rates should be matched to conditions. Use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits.
Respiratory Protection : If engineering controls do not maintain airborne concentrations below recommended exposure limits, an approved respirator must be worn. If respirators are used, a program should be instituted to assure compliance with NOISH standard 29 CFR 1910 SUBPART Z.
Eye protection : Wear safety glasses with side shields. (or goggles)
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9. Physical and Chemical Properties.
Appearance : Solid like white cotton.
Smell : Stimulus smell of Isopropylalcohol
Molecular weight : 247.2 ~ 266.5
Boiling point : None Known
Melting point : None Known
Explosiveness at humidity : None (possible at dry situation)
Steam pressure: none known
Steam density : none known
Specific gravity : 1.66
PH : NONE KNOWN
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10. Stability and Reactivity
Chemical stability and reactivity - Nitrocellulose at dry may explosive
Conditions to avoid - fire, flammable, spark, dry, impact
Material to avoid
Nitrocellulose (humidity)
- Strong Alkali – Danger of fire or explosive
Isopropylalcohol
- Acid, Aluminum, peroxide, halogen, barium, ketone, nitro, phosgene, oxygen, Oxidizer
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11. Toxicological Information
Nitrocellulose
Immediate infection toxicology : None Known
Immediate injectant toxicology : None Known
Immediate inhalation toxicology : None Known
Immediate toxicology : None Known
Slow toxicology : None Known
Changeable effect : None Known
Isopropylalcohol
Carcinogenic : IARC(group 3) –Insufficiency of evidence for human and animal.
IARC (group 1) – Shown increasing laryngeal cancer who participates in Isopropylalcohol manufacturing.
Immediate Toxicology : little toxicology by skin inhalation or Ingestion.
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12. Ecological Information
Living and Ecologic Toxicology : None known
Soil moving : None Known
Dissolution : None Known
Storing in animal and living things : None Known
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13.Disposal Considerations
Discharge, treatment, or disposal may be subject to national, state, or local laws, 40 CFR 262 standard. Mix with compatible chemical which is less flammable and incinerate.
EPA Hazard waste No. : D003
CERCLA 103 RQ : 100 POUND
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14.Transport Information
Hazard transport or Storage regulation
CLM/RID Class 4-1, 7th a- 7th h
ADR Class 4-1, 7th a –7th h
Transport cautions
Should show product name and quantity on Drum
Do not impact or drop
Keep drum out of direct rays of the sun
Move drum or stop truck in absolutely safe place
Damaged drum during moving should be removed immediately
Foreign transport regulation
US DOT shipment name and ID no. (49CFR 172.101) : Nitrocellulose UN0342
US DOT hazard classification (49CFR 172.101) : 1.3 – explosives
US DOT packing standard (49CFR 172.101) : PG II
US DOT limits (49CFR 172.101) :
: Airplane for passengers or train : not allowed
: Airplane for freight : not allowed
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15.Regulatory Information
Republic of Korea
Industrial safety health measures : Regulation
Hazard chemical material Administration : Regulation
Fire service Act : regulation (5 sort)
Foreign regulations
TSCA : regulation
CERCLA Article 103 (40 CFR 302.4) : none regulation
SARA Article 302 (40 CFR 355.30) : none regulation
SARA Article 304 (40 CFR 355.40) : none regulation
SARA Article 313 (40 CFR 372.65) : none regulation
OSHA OFFICAL SAFETY ADMINISTRATION (29 CFR 1910.119) : none regulation
CALIFORNIA SUGGESTION 65 : none regulation
SARA HAZARD CLASSIFICATIONS - Article 311/312 (40 CFR 370.21) : Fire Hazard, immediate health hazard, reaction hazard, slow hazard, immediate explosive hazard
译文:
物质安全说明书
(硝化纤维)
1. 产品及公司信息
.物质名称:硝化纤维
美国化学文摘社登记号(CAS#):9004-70-0
化学物质毒性数据库登记号(RTECS#):QW 0975200
UN编号:2556
产品名称:硝化棉
分子式:C6H7(OH)2 ONO2
危害类别:高度易燃物质
用途:用于油漆,油墨,粘合剂,香烟过滤嘴,美甲用品,荧光粉,人造皮革,磁带等制造。
厂家及供应商信息:
厂家:KOREA C & C CO., LTD.
地址:821 YONGAMRI, BONGDONGYEP, WANJU, JUNBUK, KOREA
电话:063 260 2072
传真:0653 262 0021
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2. 产品成分信息
成分:
硝化纤维(硝化棉)
百分比:70%
异丙醇(二甲基乙醇)
美国化学文摘社登记号(CAS#):67-63-0
百分比:30%
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3. 危害识别
美国消防协会等级(NFPA RATINGS)(0-4):健康危害=0,可燃性=3,反应活性=3
美国职业与安全管理局(OSHA):无相关规定。
美国国家毒理学项目组(NTP):无相关规定。
国际癌症研究机构(IARC):无相关规定。
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4. 急救措施
吸入后:撤离至空气清新处。弱旅呼吸停止,尝试人工呼吸。就医。
皮肤接触后:使用合适的清洗剂清洗。使用清水和肥皂清洗。就医。
眼睛接触后:立即用大量清水冲洗,就医。
吞食后:在没有专业人士的指导下,请勿催吐。立即就医。
▶紧急处理措施:
穿戴合适的防护性衣物/设备。
清除所有危险源。
请勿排入河道或下水道。
少量泄漏,擦除即可。
大量泄漏,使用沙或泥土吸附。
收集后参照当地相关法规进行处置。
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5. 消防措施
美国职业与安全管理局(OSHA)火灾分类:1B
燃点:约180℃
灭火介质:喷水,干粉,二氧化碳及泡沫灭火剂。
特殊消防措施:佩戴自给式呼吸器,穿着防护性衣物。用喷水冷却置于火种的密闭容器。用水灭火可能不是非常有效。
特殊火灾及爆炸危害:该物质可燃。蒸汽可能引起闪火或具有爆炸性。由于蒸汽能散发一定距离,遇上火源会产生反燃。防止蒸汽或气体聚集至可能引发爆炸危险的浓度。
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6. 意外泄漏处置措施
移除所有着火源。用蛭石或其它惰性材料吸附泄漏物,收集至专门处置化学品废弃物的容器中。
大量泄漏:用晒水分散蒸汽,冲洗泄漏地面。防止冲洗废弃物进入排水沟,下水道或河道中。
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7. 处置与储存
容器保持密闭。容器存放于干燥阴凉处,远离着火源,保持良好通风,遵循法规29CFR 1910.106。防止吸入蒸汽。实行良好的员工卫生条例。选用通风良好场所。
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8. 接触控制/个人防护
接触极限值(异丙醇):
OSHA PEL : TWA (400 PPM), STEL (500 PPM)
ACGIH TLV : TWA (400 PPM), STEL (500 PPM)
NIOSH REL : TWA (400 PPM), STEL (500 PPM)
备注:
OSHA-职业安全与健康署
ACGIH-美国政府工业卫生学家协会
NIOSH-美国职业安全与健康国立研究所
TLV-阈限值
PEL-可允许暴露极限值
TWA-时间加权平均阈限值
REL-推荐使用的暴露极限值
通风措施:使用良好的通风措施,根据实际情况调节通风强度。密闭操作,采用局部通风或其它工程控制措施,使空气浓度控制在规定接触极限值之下。
呼吸系统防护:如果空气浓度高于推荐的接触极限值,必须佩戴经许可的呼吸器,呼吸器必须符合NOISH参照法规29CFR 1910 Z章节制定的标准。
眼睛防护:佩戴两侧有防护的安全防护眼镜(或护目镜)。
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9. 理化特性
外表:固体,类似于白色棉花
气味:带有异丙醇的刺激性气味
分子量:247.2 ~ 266.5
沸点:未知
熔点:未知
在潮湿中的爆炸性:无(在干燥的环境中潜在爆炸危险)
蒸汽压:未知
蒸气密度:未知
比重:1.66
PH值:未知
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10. 稳定性与反应性
稳定性及反应性:在干燥环境中,硝化纤维具有爆炸可能性。
应避免的条件:火源,易燃物质,火花,干燥环境,冲击。
.应避免的物质:
硝化纤维(在潮湿环境中)
-强碱-具有火灾或爆炸危害
异丙醇
-酸,铝,过氧化物,卤素,钡,酮,硝基物质,碳酰氯,氧气,氧化剂
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11. 毒性数据
硝化纤维:
即时传感毒性:未知
即时注射毒性:未知
即时吸入性毒性:未知
即时毒性:未知
慢性毒性:未知
可变效应:未知
异丙醇:
致癌性:IARC(3类)-未有充足资料证明对人体及动物有致癌性。
IARC(1类)-对于参与异丙醇生产的人员,患喉癌的可能性逐渐增大。
即时毒性:经皮,吸入或吞食,低毒。
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12. 生态数据
生物及生态毒性:未知
在土壤中的迁移性:未知
降解性:未知
在动物及生物中的蓄积性:未知
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13. 废弃处置
参照联邦,州立或当地法规 40CFR 262对废弃物进行排放,处理或处置。与相对该物质,不易燃的兼容化学品混合,然后进行焚烧。
EPA有害废弃物编码:D003
CERCLA 103 RQ:100磅
备注:
EPA-美国环境保护署
CERCLA-综合环境反应补偿与责任法
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14. 运输资料
有害物质运输或储存相关法规:
CLM/RID 分类:4-1类,7th a- 7th h
ADR 分类:4-1类,7th a- 7th h
运输注意事项:
在容器上应标明产品名称及数量
防止冲击或坠落
容器避免阳光直射
在绝对安全的地方搬运或停留
立即清除在运输过程中破损的容器
国际运输法规:
美国DOT装运名称及UN编号(参照法规49CFR 172.101):硝化纤维,UN 0342
美国DOT危害类别(参照法规49CFR 172.101):1.3类爆炸性物质
美国DOT包装类别(参照法规49CFR 172.101):II类
美国DOT运输限制(参照法规49CFR 172.101):
火车运输:不允许
空运:不允许
备注:
CLM:美国物流管理
RID:国际铁路运输危险货物条例
ADR:欧洲国际公路运输危险货物协定
DOT:(美国)交通运输部
15. 法规信息
韩国法规:
工业卫生与健康条例:作了相关规定
有害化学品物质管理条例:作了相关规定
消防法:作了相关规定(5类)
国际法规:
有毒物质控制法案(TSCA):作了相关规定
综合环境反应补偿与责任法(CERCLA )103部分(参照法规40 CFR 302.4):未规定
非常基金修正及再授权法(SARA)第302部分规定(参照法规40 CFR 355.30):未规定
非常基金修正及再授权法(SARA)第304部分规定(参照法规40 CFR 355.40):未规定
非常基金修正及再授权法(SARA)第313部分规定(参照法规40 CFR 372.65):未规定
美国职业与安全管理局(OSHA)(参照法规29 CFR 1910.119):未规定
加州65:未规定
非常基金修正及再授权法(SARA)危害类别:第311/312部分(参照法规40 CFR 370.21):火灾危害,即时健康危害,反应性危害,慢性危害,即时爆炸危害
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