产品名称           ：168 #不饱和聚酯树脂

生产企业名称    

地址              

邮编              

应急电话          

传真电话          

手机               

网址              

邮箱               

 

 

 

组分           ：聚合物的溶液（混合物）

 

 

 

 

 

 

 

对人类健康的危害   ：可燃，会刺激皮肤、眼和呼吸道

 

作用方式及症状

-吸入               ：咳嗽、头痛、头昏、困倦、意识模糊、恶心和呕吐

-误服                   ：喉咙剧痛、胃痛、头疼、头昏、呕吐、麻木

-接触皮肤病         ：皮肤干裂、变红

-接触眼睛           ：疼痛、变红

 

 

 

 

 

急救措施

-吸入               ：立即移至有新鲜空气处，休息；半立直姿势，解开衣扣以利于呼吸如果呼吸困难应立即进行人工呼吸。中毒严重者应立即送医院救治。

-误服               ：注意：千万不可催吐以免因呼吸不当对人身造成危害。可用清水漱口或去 医院治疗。

-接触皮肤           ：立即用大量肥皂水冲洗，脱掉所有被污染的衣物，情况来严重的送医院治疗。

-接触眼睛           ：立即用大量清水冲洗，把眼睑向上翻，尽量与眼球分工以确保残余有害物质被冲洗干净，然后心须送医院治疗

                    

 

 

 

灭火介质

-适用的灭火器种类    ：干粉、二氧化碳、泡沫、水（仅限于大面积失火）

-有害热分解产物     ：燃烧会产生有毒气体

-灭为者的保护       ：穿防护服并使用自备呼吸装置

 

 

 

 

个人防护措施       ：佩带合适的个人防护器械，避免吸入有害气体。

 

 

 

保护环境措施和清洗方法 ：防止污染物进下水道、表面水、地下水和土壤。尽可能将            有害物质收集到一个干净的容器内等待处理，用惰性吸附剂覆盖在残余的有害物质上。根据地方的有关法规处理。

 

 

操作              ：远离热源、远离点火源。严禁吸烟。避免吸入有害气体。避免接触到眼睛和皮肤，采取措施，防止静电。

储存              ：应储存在温度较低、通风良好的地方，避免接触过氧化物，采取措施防止静电，当含有苯乙烯的不饱和聚酯树脂暴露到光线下时，其储存期将显著缩短，存放在100%不透光的容器内，置于阴暗处。

 

 

 

 

工作环境中有害物质含量的极限值

 

 

 

 

个人防护设施       

-呼吸系统工程       ：工作环境中有害物质含量决不能超过极限值，可以使用局部的通风系统或在通风橱内操作。为了更好的保护脸部建议使用防毒面罩。

-皮肤和身体         ：化学防护服；耐化学防护鞋。

-手部                ：耐化学防护手套（丁基合成橡胶，聚会乙烯醇）

- 眼睛                ：有防护边的安全眼镜。

 

 

 

  物理状态有外观   ：液体

   颜色             ：淡黄

   气体             ：典型

   沸点            ：已知最低值145℃（293℉）（苯乙烯）

   熔点               ：-30℃（-22.9℉）开始向固态转变（基于苯乙烯的物性数据）

   体积密度           ：1.1g/cm3

   蒸汽密度           ：已知最高值3.6（空气-1）（苯乙烯）

   蒸汽压            ：已知最高值0.6KPa(4.5mmHg,20℃) （苯乙烯）

   溶解性            ：不溶于冷水

   辛醇/水溶解系       ：不适用

   PH值             ：不适用

   闪点               ：封闭的杯子：33℃（91.4℉）

   自燃点             ：已知最低温度490℃（914℉）（苯乙烯）

   空气中爆炸极限     ：已知最大范围为：1.1%-8%（苯乙烯）

   粘度（23℃）      ：》300mPa.s

 

 

 

 

应避免的外界环境     ：过热，阳光直射。

应避免接触的材料     ：不可与过氧化物混合

有危害的分解产物     ：无

 

 

 

 

急性动物实验毒性数据

(ld50,lc50)           ：急性口服毒性数据（ld50）：316mg/kg(老鼠) （苯乙烯）.

                            急性气体毒性数据（lc50）：4000ppm 4小时(老鼠) （苯乙烯）

 

 

 

 

流动性               ：无数据

持久性/分解性         ：无数据

潜在的生物积累性     ：无数据

环境毒性             ：无数据

 

 

 

 

处理方法             ： 在严格的控制下焚烧。注意在空容器中有残余的溶剂气体应远

（包括废弃的残渣          离火源，防止爆炸和有毒气体泄露。只有有资质的废桶处理机

和被污染的包装）           构方可处理。

 

 

 

 

国际运输规则

-UN号                  ： 1866                     ADR/RID Label

陆地---公路/铁路

- 适当运输名称          ：树脂溶液，可燃

-ADR/RID 等级          ：3

-ADR/RID条款数值       ：不适用

-包装级别                ：Ⅲ

-危险物品证书号          ：30-1866

海运

-适当运输名称            ：树脂溶液，可燃

-IMDG等级              ：3.3

-IMDG页号（GB）       ：3379

-包装级别                ：Ⅲ

-药物急救指导（MFAG） ：310

-紧急情况处理表（EmS） ：3-05

-海洋污染物质            ：污染

空运

-适当运输名称            ：树脂溶液，可燃

   -UN/ID号                ：1866

   -IATA-DGR 等级          ：3

 

 

 

Product Name: 168 # Unsaturated Polyester Resin

Manufacturer:

Address:

Post Code:

Emergency Call:

Fax.:

Cell Phone:  

Web Site:

Email:  

 

Composition: Polymer solution (mixture)

 

 

 

 Health Hazards: Flammable. It is irritating to skin, eyes and respiratory system. 

Entry Routes and Symptoms:

-Inhalation: Symptoms contain coughing, headache, dizziness, drowsiness, mental vagueness, nausea and vomiting.

-Ingestion: Symptoms contain throat pain, headache, dizziness, vomiting and anaesthesia.

-Skin Contact: It causes skin dry and redness.

-Eyes Contact: It causes pain and redness.

 

 

 

-Inhalation: Immediately remove to fresh air and have a rest. Bend a little down and unbutton clothes to make sure no difficulty in breathing. Give artificial breathing, if breathing is difficult. Immediately take the severely poisoned persons to hospital for medical care.

-Ingestion: Caution: Do not induce vomiting to avoid inducing harm to body as inducing vomiting

may cause hard breathing.

Rinse the mouth with clean water or get medical care.

-Skin Contact: Immediately flush contaminated skin with plenty of suds. Take off contaminated clothing. Get medical care for obvious discomfort.

-Eyes Contact: Immediately raise eyelids and flush with plenty of water. Make sure there is no residual in the eyes. Get medical care.                    

 

 

 

Fire-Extinguishing Media:

-Proper Fire-Extinguishing Agents: Dry powder, carbon dioxide, foam and water (only effective for extensive fire).

-Hazardous Combustion Products: Toxic gas can be released from combustion.

-Protection for Fire-Fighting: Wear protective clothing and use self-contained breathing apparatus.

 

 

Personal Protection: Wear proper protective apparatus. Avoid inhaling hazardous gas.

 

Environmental Protection and Cleaning Methods: Prevent pollutants from entering sewers surface water, ground water and soil. Collect hazardous materials into a clean container for proper disposal. Absorb residual with inert materials. Dispose according to relevant local laws and regulations.

 

 

Handling: Stay away from heat and fire sources. No smoking. Avoid inhaling hazardous gas. Avoid eyes and skin contact. Take precautions to avoid static electricity releasing.

Storage: Store in a cool and well-ventilated place. Do not store together with peroxides. Take effective precautions for static electricity. The time for storage will be shorter if this product is exposed to sunlight as it contains styrene. Store it in a fully sealed container and put it in a cool and dry place.

 

 

 Exposure Limits for Hazardous Substances in Working Place:

 

 

 

Personal Protection:

-Respiratory Protection: Use local exhaust or operate in a fume hood to keep the exposure limits of hazardous substances in the recommended ones. Use a protective respirator to protect face.

-Skin and Body Protection: Wear chemical protective clothing and chemical protective shoes.

-Hands Protection: Wear chemical protective gloves. (e.g. Butyl gloves, PVA gloves)

- Eyes Protection: Wear safety goggles with side protection.

 

 

 

Physical State: Liquid

Color: Light yellow

Odor: Characteristic

Boiling Point: Min. 145℃（293℉）（Styrene）

Melting Point: -30℃（-22.9℉）（Styrene）

Bulk Density: 1.1 g/cm³

Vapor Density: Max. 3.6（air=1）（Styrene）

Vapor Pressure: Max. 0.6KPa (4.5mmHg,20℃) （Styrene）

Solubility: Soluble in cold water

n-octanol/Water Partition Coefficient: Not applicable

PH: Not applicable

Flash Point: Closed Cup 33℃（91.4℉）

Self-Ignition Temperature: Min. 490℃（914℉）（Styrene）

Explosion Limit in Air: Max. 1.1%-8%（Styrene）

Viscosity （23℃）: ＞300mPa.s

 

 

Conditions to be avoided: Extreme heat and direct sunlight.

Materials to be avoided: Do not mix with peroxides.

Hazardous Decomposition Products: Not found.

 

 

Acute Toxicological Data

(LD50, LC50): Acute Oral: LD50: 316mg/kg (rat) （Styrene）.

                       Acute Gas Toxicological Data（LC50）: 4000ppm 4 hours (rat) （styrene）

 

 

Mobility in Soil: No data.

Persistence/Degradability: No data.

Potential Bioaccumulation: No data.

Ecological Toxicity: No data.

 

 

Disposal Method (including residual and contaminated package): Adopt incineration with strict control. The empty container may contain solvent vapor. Stay away from fire. Take precautions for explosion and toxic gas release. Transport the waste to a qualified agency for proper disposal.

 

 

International Transportation Regulations:

-UN Code: 1866                    

ADR/RID Label

- Proper Shipping Name: Resin solution, flammable

-ADR/RID Class: 3

-Packing Group: Ⅲ

-Dangerous Goods Certificate No.: 30-1866

IMDG

-Proper Shipping Name: Resin solution, flammable

-IMDG Class: 3.3

-IMDG Code: 3379

-Packing Group: Ⅲ

- MFAG: 310

- EmS: 3-05

Ocean Pollutants: YES

IATA-DGR

-Proper Shipping Name: Resin solution, flammable

-UN/ID Code: 1866

-IATA-DGR Class: 3